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oxidation of benzyl alcohol

Dual Stimuli-Responsive Copper Nanoparticles Decorated SBA-15: A Highly Efficient Catalyst for the Oxidation of Alcohols in Water. Pd doped Co functionalized SBA-15 as an active magnetic catalyst for low temperature solventless additive-base-free selective oxidation of benzyl alcohol. Manman Jin, Qingtao Niu, Chongdian Si, Zhiguo Lv, Hongyue Guo, Zhenmei Guo. Visible Light Photocatalytic Aerobic Oxygenation of Indoles and pH as a Chemoselective Switch. a During the photocatalytic process, molecular oxygen was not incorporated into the final benzaldehyde and only involved in the oxidation of Cu(I) into Cu(II) in which it served as a terminal hydrogen acceptor to form H2O. http://pubs.acs.org/page/copyright/permissions.html. Highly efficient and selective photocatalytic dehydrogenation of benzyl alcohol for simultaneous hydrogen and benzaldehyde production over Ni-decorated Zn0.5Cd0.5S solid solution. Dimethyl sulfoxide as a “methylene” source: Ru( Find more information on the Altmetric Attention Score and how the score is calculated. Min Zhou, Pengju Yang, Sibo Wang, Zhishan Luo, Caijin Huang, Xinchen Wang. Please enable JavaScript Synthesis of surface controlled nickel/palladium hydride nanodendrites with high performance in benzyl alcohol oxidation. Anju Maria Thomas, Jerome Peter, Saravanan Nagappan, Anandhu Mohan, Chang-Sik Ha. Daochuan Jiang, Xin Chen, Zhuang Zhang, Lei Zhang, Yang Wang, Zijun Sun, Rana Muhammad Irfan, Pingwu Du. Instructions for using Copyright Clearance Center page for details. 3 XX is the XXth reference in the list of references. Jingwen Chen, Haifeng Xiang, Li Yang, Xiangge Zhou. Photocatalytic Oxidation of Benzyl Alcohol by Homogeneous CuCl, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350002, P. R. China. Solvent-free photo-thermocatalytic oxidation of benzyl alcohol on Pd/TiO2 (B) nanowires. E-mail: Visible‐Light‐Enabled Selective Oxidation of Primary Alcohols through Hydrogen‐Atom Transfer and its Application in the Synthesis of Quinazolinones. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. A similar role of molecular oxygen has also been observed in the heterogeneous TiO2 photocatalytic system. ii Synthesis of 2-substituted benzo[b]thiophene via a Pd-catalyzed coupling of 2-iodothiophenol with phenylacetylene. These metrics are regularly updated to reflect usage leading up to the last few days. 2. A Green and Effective Approach of Two-Step 2,2′,4,4′,6,6′-Hexanitrostilbene Preparation and Its Industrial Scale Study. You do not have JavaScript enabled. Copyright © 2012 Elsevier Ltd. All rights reserved. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. If you are the author of this article you do not need to formally request permission ) complex catalyst. Gabriele Scandura, Giovanni Palmisano, Sedat Yurdakal, Bilge Sina Tek, Levent Özcan, Vittorio Loddo, Vincenzo Augugliaro. redistribute this material, requesters must process their own requests via the RightsLink permission The methodology that involves mere stirring/heating of the reactants and oxone in acetonitrile/water (1:1, v/v) is simple and practical, but is limited to substrates that do not contain sensitive functionalities and heteroaromatic … to reproduce figures, diagrams etc. Department of Chemistry, University of Stellenbosch, Private Bag X1, Matieland, South Africa Case Study 1: Magnetic Pd Catalysts for Benzyl Alcohol Oxidation to Benzaldehyde. Qiangqiang Xia, Zuodong Shi, Jiangpei Yuan, Qilong Bian, Yuanqing Xu, Baoying Liu, Yongwei Huang, Xiaobo Yang, Hao Xu. It was found that the selectivity to benzaldehyde is strongly dependent on the level of chloride ion, which leads to the formation of dibenzyl ether. Secondly, the amount of water present in the ionic liquid determines the extent of benzoic acid formation. All extra reaction data, additional crystallographic information, and the copies of mass spectra for all the resulted products in different reactions (PDF). In order to provide a methodology that addresses these problems, ionic liquids have been investigated as reaction media. The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Files available from the ACS website may be downloaded for personal use only. Industrially performed catalytic oxidation reactions often suffer from drawbacks such as poor conversion and selectivity due to over-oxidation, corrosive reaction media, lack of solvent and catalyst recycling, and negative environmental impact due to evaporation of the solvents. Lam, Xijun Hu. The understanding of the role of molecular oxygen helps us to further design new classes of synthetic organic reactions by photocatalytic processes. Lei Zhang, Daochuan Jiang, Rana Muhammad Irfan, Shan Tang, Xin Chen, Pingwu Du. We use cookies to help provide and enhance our service and tailor content and ads. Your Mendeley pairing has expired. For permission to reproduce, republish and 32+. Cancan Ling, Xiangju Ye, Jinghu Zhang, Jinfeng Zhang, Sujuan Zhang, Sugang Meng, Xianliang Fu, Shifu Chen. astark@akad.sun.ac.za. Reproduced material should be attributed as follows: If the material has been adapted instead of reproduced from the original RSC publication 36 publications. k.seddon@qub.ac.uk, b Information about reproducing material from RSC articles with different licences Find more information about Crossref citation counts. with the reproduced material. Solvothermal synthesis of CdIn2S4 photocatalyst for selective photosynthesis of organic aromatic compounds under visible light. "Reproduced from" can be substituted with "Adapted from". it in a third party non-RSC publication you must Switchable Bifunctional Bistate Reusable ZnO–Cu for Selective Oxidation and Reduction Reaction. Lele Wang, Wei Wang, Ming Liu, Huaqi Ge, Wenying Zha, Yingcong Wei, Enhu Fei, Zizhong Zhang, Jinlin Long, Rongjian Sa, Yan-jie Wang, Xianzhi Fu, Rusheng Yuan. Electronic Supporting Information files are available without a subscription to ACS Web Editions. ) in (b) correspond to the benzyl alcohol oxidation reaction under the dewetted slug flow at elevated temperature conditions (150 C and 1 bar), where mass transfer limitations were observed (i.e., U M You have to login with your ACS ID befor you can login with your Mendeley account. Benzyl alcohol is produced industrially from toluene via benzyl chloride, which is hydrolyzed: E-mail: Pengcheng Wang, Ting-ting Lu, and Ming Lu . Peroxotungstate-Based Ionic Hybrid as a Triphase Heterogeneous Catalyst for Efficient Benzyl Alcohol Oxidation Under Mild Conditions. ) photo-catalysed facile synthesis of acetals from alcohols. Structure-Mediated Charge Separation in Boron Carbon Nitride for Enhanced Photocatalytic Oxidation of Alcohol. The oxidation of alcohols to the corresponding carbonyl compounds is a pivotal reaction in organic synthesis. Transition Metal-Catalyzed Organic Reactions under Visible Light: Recent Developments and Future Perspectives. Information about how to use the RightsLink permission system can be found at )/graphene oxide foam: a sustainable catalyst for the oxidation of benzyl alcohol to benzaldehyde. Under visible light irradiation, the homogeneous CuCl2 and cheap solvent oxidized benzyl alcohol into benzaldehyde with a selectivity higher than 95% using molecular oxygen as an oxidant. Journal of Photochemistry and Photobiology A: Chemistry. Go to our Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. Bao Zhang, Jun Li, Yuying Gao, Ruifeng Chong, Zhiliang Wang, Lin Guo, Xianwen Zhang, Can Li. Waldemar Schilling, Daniel Riemer, Yu Zhang, Nareh Hatami. Under visible light irradiation, the homogeneous CuCl2 and cheap solvent oxidized benzyl alcohol into benzaldehyde with a selectivity higher than 95% using molecular oxygen as an oxidant. system. Visible light-induced selective aerobic oxidative transposition of vinyl halides using a tetrahalogenoferrate( Visible light mediated chemo-selective oxidation of benzylic alcohols. ScienceDirect ® is a registered trademark of Elsevier B.V. ScienceDirect ® is a registered trademark of Elsevier B.V. Oxidation of benzyl alcohols, benzyl halides, and alkylbenzenes with oxone. Pengcheng Lian, Wenhao Long, Jingjing Li, Yonggao Zheng, Xiaobing Wan. Photochemical oxidation of benzylic primary and secondary alcohols utilizing air as the oxidant. Catalytic Aerobic Oxidation of C(sp do not need to formally request permission to reproduce material contained in this Yingying Li, Jiale Huang, Xijun Hu, Frank Leung-Yuk Lam, Wenju Wang, Rafael Luque. For reproduction of material from all other RSC journals and books: For reproduction of material from all other RSC journals. Xiaochen Ji, Dongdong Li, Zhongzhen Wang, Muyun Tan, Huawen Huang, Guo-Jun Deng. Mingming Du, Ganning Zeng, Changhui Ye, Hao Jin, Jiale Huang, Daohua Sun, Qingbiao Li, Bing Chen, Xiaonian Li. )−H Bonds. The oxidation of toluene and ethylbenzene showed that the introduction of oxygen into the molecule is feasible using the same methodology. Sanliang Li, Bo Zhu, Richmond Lee, Baokun Qiao, Zhiyong Jiang. The formation of a visible light responsive complex between Cu(II) and solvent is responsible … Marrying SPR excitation and metal–support interactions: unravelling the contribution of active surface species in plasmonic catalysis. This may take some time to load.

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